HAL (France)
open access
Catalytic Enantioselective Synthesis of Conformationally Stable C(sp 2 )−C(sp 3 ) Naphthocoumarin Atropisomers
A straightforward atroposelective access to enantiomerically enriched 2‐hydroxy‐3‐(2‐oxochroman‐4‐yi)naphthalene‐1,4‐diones (with yields ranging from 32% to 87% and enantiomeric excesses up to 99%) is described. Using an organocatalytic approach, 2‐hydroxynaphthoquinone reacts with a 3‐coumarin‐3‐ca
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