40 CFR Part 419 — Petroleum Refining Point Source Category

PART 419—PETROLEUM REFINING POINT SOURCE CATEGORY Authority: Secs. 301, 304 (b), (c), (e), and (g), 306 (b) and (c), 307 (b) and (c), and 501 of the Clean Water Act (the Federal Water Pollution Control Act Amendments of 1972 as amended by the Clean Water Act of 1977) (the “Act”); 33 U.S.C. 1311, 1314 (b), (c), (e), and (g), 1316 (b) and (c), 1317 (b) and (c), and 1361; 86 Stat. 816, Pub. L. 92-500; 91 Stat. 1567, Pub. L. 95-217. Source: 47 FR 46446, Oct. 18, 1982, unless otherwise noted. Subpart A—Topping Subcategory § 419.10 Applicability; description of the topping subcategory. The provisions of this subpart apply to discharges from any facility that produces petroleum products by the use of topping and catalytic reforming, whether or not the facility includes any other process in addition to topping and catalytic reforming. The provisions of this subpart do not apply to facilities that include thermal processes (coking, vis-breaking, etc.) or catalytic cracking. § 419.11 Specialized definitions. For the purpose of this subpart: (a) Except as provided below, the general definitions, abbreviations, and methods of analysis set forth in part 401 of this chapter shall apply to this subpart. (b) The term runoff (c) The term ballast (d) The term feedstock (e) The term once-through cooling water (f) The following abbreviations shall be used: (1) Mgal means one thousand gallons; (2) Mbbl means one thousand barrels (one barrel is equivalent to 42 gallons). (g) The term contaminated runoff [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28522, July 12, 1985] § 419.12 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT): Pollutant or pollutant property BPT Effluent Limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 22.7 12.0 TSS 15.8 10.1 COD 1 117.0 60.3 Oil and grease 6.9 3.7 Phenolic compounds 0.168 0.076 Ammonia as N 2.81 1.27 Sulfide 0.149 0.068 Total chromium 0.345 0.20 Hexavalent chromium 0.028 0.012 pH ( 2 ( 2 English units (pounds per 1,000 bbl of feedstock) BOD 5 8.0 4.25 TSS 5.6 3.6 COD 1 41.2 21.3 Oil and grease 2.5 1.3 Phenolic compounds 0.060 0.027 Ammonia as N 0.99 0.45 Sulfide 0.053 0.024 Total chromium 0.122 0.071 Hexavalent chromium 0.01 0.0044 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 1.02 25.0 to 49.9 1.06 50.0 to 74.9 1.16 75.0 to 99.9 1.26 100 to 124.9 1.38 125.0 to 149.9 1.50 150.0 or greater 1.57 (2) Process factor. Process configuration Process factor Less than 2.49 0.62 2.5 to 3.49 0.67 3.5 to 4.49 0.80 4.5 to 5.49 0.95 5.5 to 5.99 1.07 6.0 to 6.49 1.17 6.5 to 6.99 1.27 7.0 to 7.49 1.39 7.5 to 7.99 1.51 8.0 to 8.49 1.64 8.5 to 8.99 1.79 9.0 to 9.49 1.95 9.5 to 9.99 2.12 10.0 to 10.49 2.31 10.5 to 10.99 2.51 11.0 to 11.49 2.73 11.5 to 11.99 2.98 12.0 to 12.49 3.24 12.5 to 12.99 3.53 13.0 to 13.49 3.84 13.5 to 13.99 4.18 14.0 or greater 4.36 (3) See the comprehensive example Subpart D, § 419.42(b)(3). (c) The following allocations constitute the quantity and quality of pollutants or pollutant properties controlled by this paragraph and attributable to ballast, which may be discharged after the application of best practicable control technology currently available, by a point source subject to this subpart, in addition to the discharge allowed by paragraph (b) of this section. The allocation allowed for ballast water flow, as kg/cu m (lb/M gal), shall be based on those ballast waters treated at the refinery. Pollutant or pollutant property BPT effluent limitations for ballast water Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per cubic meter of flow) BOD 5 0.048 0.026 TSS 0.033 0.021 COD 1 0.47 0.24 Oil and grease 0.015 0.008 pH ( 2 ( 2 English units (pounds per 1,000 gal of flow) BOD 5 0.40 0.21 TSS 0.26 0.17 COD 1 3.9 2.0 Oil and grease 0.126 0.067 pH ( 2 ( 2 1 2 (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease and 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease or 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BPT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 48. 26. TSS 33. 21. COD 1 360. 180. Oil and grease 15. 8. Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.73 0.43 Hexavalent chromium 0.062 0.028 pH ( 2 ( 2 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 COD 1 3.0 1.5 Oil and grease 0.13 0.067 Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0060 0.0035 Hexavalent chromium 0.00052 0.00023 pH ( 2 ( 2 1 5 5 2 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28522, 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.13 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT): Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 COD 1 117 60.3 Ammonia as N 2.81 1.27 Sulfide 0.149 0.068 English units (pounds per 1,000 bbl of feedstock) COD 1 41.2 21.3 Ammonia as N 0.99 0.45 Sulfide 0.053 0.024 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 1.02 25.0 to 49.9 1.06 50.0 to 74.9 1.16 75.0 to 99.9 1.26 100 to 124.9 1.38 125.0 to 149.9 1.50 150.0 or greater 1.57 (2) Process factor. Process configuration Process factor Less than 2.49 0.62 2.5 to 3.49 0.67 3.5 to 4.49 0.80 4.5 to 5.49 0.95 5.5 to 5.99 1.07 6.0 to 6.49 1.17 6.5 to 6.99 1.27 7.0 to 7.49 1.39 7.5 to 7.99 1.51 8.0 to 8.49 1.64 8.5 to 9.99 1.79 9.0 to 9.49 1.95 9.5 to 9.99 2.12 10.0 to 10.49 2.31 10.5 to 10.99 2.51 11.0 to 11.49 2.73 11.5 to 11.99 2.98 12.0 to 12.49 3.24 12.5 to 12.99 3.53 13.0 to 13.49 3.84 13.5 to 13.99 4.18 14.0 or greater 4.36 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c)(1) In addition to the provisions contained above pertaining to COD, ammonia and sulfide, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT): (i) For each of the regulated pollutant parameters listed below, the effluent limitation for a given refinery is the sum of the products of each effluent limitation factor times the applicable process feedstock rate, calculated as provided in 40 CFR 122.45(b). Applicable production processes are presented in appendix A, by process type. The process identification numbers presented in this appendix A are for the convenience of the reader. They can be cross-referenced in the Development Document for Effluent Limitations Guidelines, New Source Performance Standards, and Pretreatment Standards for the Petroleum Refining Point Source Category Pollutant or pollutant property and process type BAT effluent limitation factor Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 cubic meters of feedstock) Phenolic compounds (4AAP): Crude 0.037 0.009 Cracking and coking 0.419 0.102 Asphalt 0.226 0.055 Lube 1.055 0.257 Reforming and alkylation 0.377 0.092 Total chromium: Crude 0.030 0.011 Cracking and coking 0.340 0.118 Asphalt 0.183 0.064 Lube 0.855 0.297 Reforming and alkylation 0.305 0.106 Hexavalent chromium: Crude 0.0019 0.0009 Cracking and coking 0.0218 0.0098 Asphalt 0.0117 0.0053 Lube 0.0549 0.0248 Reforming and alkylation 0.0196 0.0088 English units (pounds per 1,000 bbl of feedstock) Phenolic compounds (4AAP): Crude 0.013 0.003 Cracking and coking 0.147 0.036 Asphalt 0.079 0.019 Lube 0.369 0.090 Reforming and alkylation 0.132 0.032 Total chromium: Crude 0.011 0.004 Cracking and coking 0.119 0.041 Asphalt 0.064 0.022 Lube 0.299 0.104 Reforming and alkylation 0.107 0.037 Hexavalent chromium: Crude 0.0007 0.0003 Cracking and coking 0.0076 0.0034 Asphalt 0.0041 0.0019 Lube 0.0192 0.0087 Reforming and alkylation 0.0069 0.0031 (2) See the comprehensive example in subpart D, § 419.43(c)(2). (d) The following allocations constitute the quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to ballast, which may be discharged after the application of best available technology economically achievable by a point source subject to the provisions of this subpart. These allocations are in addition to the discharge allowed by paragraph (b) of this section. The allocation allowed for ballast water flow, as kg/cu m (lb/M gal), shall be based on those ballast waters treated at the refinery. Pollutant or pollutant property BAT effluent limitations for ballast water Maximum for any 1 day Average or daily values for 30 consecutive days shall not exceed Metric units (kilograms per cubic meter of flow) COD 1 0.47 0.24 English units (pounds per 1,000 gal of flow) COD 1 3.9 2.0 1 5. If in the judgment of the Regional Administrator, adequate correlation data are not available, the effluent limitations for TOC shall be established at a ratio of 2.2 to 1 to the applicable effluent limitations on BOD 5. (e) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (f) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BAT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.60 0.21 Hexavalent chromium 0.062 0.028 COD 1 360. 180. English units (pounds per 1,000 gallons of flow) Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0050 0.0018 Hexavalent chromium 0.00052 0.00023 COD 1 3.0 1.5 1 5 5 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.14 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). (a) Any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (Kilograms per 1,000 m 3 BOD 5 22.7 12.0 TSS 15.8 10.1 Oil and Grease 6.9 3.7 pH ( 1 ( 1 English units (pounds per 1,000 bbl of feedstock) BOD 5 8.0 4.25 TSS 5.6 3.6 Oil and Grease 2.5 1.3 P H ( 1 ( 1 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 1.02 25.0 to 49.9 1.06 50.0 to 74.9 1.16 75.0 to 99.9 1.26 100 to 124.9 1.38 125.0 to 149.9 1.50 150.0 or greater 1.57 (2) Process factor. Process configuration Process factor Less than 2.49 0.62 2.5 to 3.49 0.67 3.5 to 4.49 0.80 4.5 to 5.49 0.95 5.5 to 5.99 1.07 6.0 to 6.49 1.17 6.5 to 6.99 1.27 7.0 to 7.49 1.39 7.5 to 7.99 1.51 8.0 to 8.49 1.64 8.5 to 8.99 1.79 9.0 to 9.49 1.95 9.5 to 9.99 2.12 10.0 to 10.49 2.31 10.5 to 10.99 2.51 11.0 to 11.49 2.73 11.5 to 11.99 2.98 12.0 to 12.49 3.24 12.5 to 12.99 3.53 13.0 to 13.49 3.84 13.5 to 13.99 4.18 14.0 or greater 4.36 (3) See the comprehensive example in subpart D, § 419.43(b)(3). (c) The following allocations constitute the quantity and quality of pollutants or pollutant properties controlled by this paragraph and attributable to ballast, which may be discharged after the application of best conventional pollutant control technology by a point source subject to this subpart, in addition to the discharge allowed by paragraph (b) of this section. The allocation allowed for ballast water flow, as kg/cu m (lb/1000 gal), shall be based on those ballast waters treated at the refinery. Pollutant or pollutant property BCT Effluent limitations for ballast water Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per m 3 BOD 5 0.048 0.026 TSS 0.033 0.021 Oil and grease 0.015 0.008 pH ( 1 ( 1 English units (pounds per 1000 gallons of flow) BOD 5 0.40 0.21 TSS 0.26 0.17 Oil and grease 0.126 0.067 pH ( 1 ( 1 1 (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BCT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 (m 3 BOD 5 48. 26. TSS 33. 21. Oil and grease 15. 8. pH ( 1 ( 1 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 Oil and grease 0.13 0.067 pH ( 1 ( 1 1 [50 FR 28524, July 12, 1985] § 419.15 Pretreatment standards for existing sources (PSES). Except as provided in 40 CFR 403.7 and 403.13 any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for existing sources (PSES). The following standards apply to the total refinery flow contribution to the POTW: Pollutant or pollutant property Pretreatment standards for existing sources maximum for any 1 day (Milligrams per liter (mg/l)) Oil and Grease 100 Ammonia (as N) 1 1 § 419.16 Standards of performance for new sources (NSPS). (a) Any new source subject to this subpart must achieve the following new source performance standards (NSPS): Pollutant or pollutant property NSPS effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per cubic meter of flow) BOD 5 11.8 6.3 TSS 8.3 4.9 COD 1 61.0 32 Oil and grease 3.6 1.9 Phenolic compounds 0.088 0.043 Ammonia as N 2.8 1.3 Sulfide 0.078 0.035 Total chromium 0.18 0.105 Hexavalent chromium 0.015 0.0068 pH ( 2 ( 2 English units (pounds per 1,000 gal of flow) BOD 5 4.2 2.2 TSS 3.0 1.9 COD 1 21.7 11.2 Oil and grease 1.3 0.70 Phenolic compounds 0.031 0.016 Ammonia as N 1.0 0.45 Sulfide 0.027 0.012 Total chromium 0.064 0.037 Hexavalent chromium 0.0052 0.0025 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 1.02 25.0 to 49.9 1.06 50.0 to 74.9 1.16 75.0 to 99.9 1.26 100 to 124.9 1.38 125.0 to 149.9 1.50 150.0 or greater 1.57 (2) Process factor. Process configuration Process factor Less than 2.49 0.62 2.5 to 3.49 0.67 3.5 to 4.49 0.80 4.5 to 5.49 0.95 5.5 to 5.99 1.07 6.0 to 6.49 1.17 6.5 to 6.99 1.27 7.0 to 7.49 1.39 7.5 to 7.99 1.51 8.0 to 8.49 1.64 8.5 to 9.99 1.79 9.0 to 9.49 1.95 9.5 to 9.99 2.12 10.0 to 10.49 2.31 10.5 to 10.99 2.51 11.0 to 11.49 2.73 11.5 to 11.99 2.98 12.0 to 12.49 3.24 12.5 to 12.99 3.53 13.0 to 13.49 3.84 13.5 to 13.99 4.18 14.0 or greater 4.36 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The following allocations constitute the quantity and quality of pollutants or pollutant properties controlled by this paragraph and attributable to ballast, which may be discharged after the application of best practicable control technology currently available, by a point source subject to this subpart, in addition to the discharge allowed by paragraph (b) of this section. The allocation allowed for ballast water flow, as kg/cu m (lb/Mgal), shall be based on those ballast waters treated at the refinery. Pollutant or pollutant property NSPS Effluent Limitations for Ballast Water Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per cubic meter of flow) BOD 5 0.048 0.026 TSS 0.033 0.021 COD 1 0.47 0.24 Oil and grease 0.015 0.008 pH ( 2 ( 2 English units (pounds per 1,000 gal of flow) BOD 5 0.40 0.21 TSS 0.27 0.17 COD 1 3.9 2.0 Oil and grease 0.126 0.067 pH ( 2 ( 2 1 2 (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (e) Effluent limitations for runoff. [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.17 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources (PSNS). (a) The following standards apply to the total refinery flow contribution to the POTW: Pollutant or pollutant property Pretreatment standards for new sources—maximum for any 1 day Milligrams per liter (mg/1) Oil and grease 100 Ammonia (as N) 1 1 (b) The following standard is applied to the cooling tower discharge part of the total refinery flow to the POTW by multiplying: (1) The standard; (2) by the total refinery flow to the POTW; and (3) by the ratio of the cooling tower discharge flow to the total refinery flow. Pollutant or pollutant property Pretreatment standards for new sources—maximum for any 1 day Milligrams per liter (mg/1) Total chromium 1 Subpart B—Cracking Subcategory § 419.20 Applicability; description of the cracking subcategory. The provisions of this subpart are applicable to all discharges from any facility that produces petroleum products by the use of topping and cracking, whether or not the facility includes any process in addition to topping and cracking. The provisions of this subpart are not applicable, however, to facilities that include the processes specified in subparts C, D, or E of this part. § 419.21 Specialized definitions. The general definitions, abbreviations and methods of analysis set forth in part 401 of this chapter and the specialized definitions set forth in § 419.11 shall apply to this subpart. § 419.22 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available: Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 28.2 15.6 TSS 19.5 12.6 COD 1 210.0 109 Oil and grease 8.4 4.5 Phenolic compounds 0.21 0.10 Ammonia as N 18.8 8.5 Sulfide 0.18 0.082 Total chromium 0.43 0.25 Hexavalent chromium 0.035 0.016 pH ( 2 ( 2 English units (pounds per 1,000 bbl feedstock) BOD 5 9.9 5.5 TSS 6.9 4.4 COD 1 74.0 38.4 Oil and grease 3.0 1.6 Phenolic compounds 0.074 0.036 Ammonia as N 6.6 3.0 Sulfide 0.065 0.029 Total chromium 0.15 0.088 Hexavalent chromium 0.012 0.0056 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 0.91 25.0 to 49.9 0.95 50.0 to 74.9 1.04 75.0 to 99.9 1.13 100.0 to 124.9 1.23 125.0 to 149.9 1.35 150.0 or greater 1.41 (2) Process factor. Process configuration Process factor Less than 2.49 0.58 2.5 to 3.49 0.63 3.5 to 4.49 0.74 4.5 to 5.49 0.88 5.5 to 5.99 1.00 6.0 to 6.49 1.09 6.5 to 6.99 1.19 7.0 to 7.49 1.29 7.5 to 7.99 1.41 8.0 to 8.49 1.53 8.5 to 8.99 1.67 9.0 to 9.49 1.82 9.5 or greater 1.89 (3) See the comprehensive example subpart D, § 419.42(b)(3). (c) The provisions of § 419.12(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease and 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease or 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BPT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 48. 26. TSS 33. 21. COD 1 360. 180. Oil and grease 15. 8. Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.73 0.43 Hexavalent chromium 0.062 0.028 pH ( 2 ( 2 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 COD 1 3.0 1.5 Oil and grease 0.13 0.067 Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0060 0.0035 Hexavalent chromium 0.00052 0.00023 pH ( 2 ( 2 1 5 5 2 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28522, 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.23 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable: Pollutant or pollutant property BAT Effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 COD 1 210 109 Ammonia as N 18.8 8.5 Sulfide 0.18 0.082 English units (pounds per 1,000 bbl of feedstock) COD 1 74.0 38.4 Ammonia as N 6.6 3.0 Sulfide 0.065 0.029 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 0.91 25.0 to 49.9 0.95 50.0 to 74.9 1.04 75.0 to 99.9 1.13 100.0 to 124.9 1.23 125.0 to 149.9 1.35 150.0 or greater 1.41 (2) Process factor. Process configuration Process factor Less than 2.49 0.58 2.5 to 3.49 0.63 3.5 to 4.49 0.74 4.5 to 5.49 0.88 5.5 to 5.99 1.00 6.0 to 6.49 1.09 6.5 to 6.99 1.19 7.0 to 7.49 1.29 7.5 to 7.99 1.41 8.0 to 8.49 1.53 8.5 to 8.99 1.67 9.0 to 9.49 1.82 9.5 or greater 1.89 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c)(1) In addition to the provisions contained above pertaining to COD, ammonia and sulfide, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT): (i) For each of the regulated pollutant parameters listed below, the effluent limitation for a given refinery is the sum of the products of each effluent limitation factor times the applicable process feedstock rate, calculated as provided in 40 CFR 122.45(b). Applicable production processes are presented in appendix A, by process type. The process identification numbers presented in this appendix A are for the convenience of the reader. They can be cross-referenced in the Development Document for Effluent Limitations Guidelines, New Source Performance Standards, and Pretreatment Standards for the Petroleum Refining Point Source Category Pollutant or pollutant property and process type BAT effluent limitation factor Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 cubic meters of feedstock) Phenolic compounds (4AAP): Crude 0.037 0.009 Cracking and coking 0.419 0.102 Asphalt 0.226 0.055 Lube 1.055 0.257 Reforming and alkylation 0.377 0.092 Total chromium: Crude 0.030 0.011 Cracking and coking 0.340 0.118 Asphalt 0.183 0.064 Lube 0.855 0.297 Reforming and alkylation 0.305 0.106 Hexavalent chromium: Crude 0.0019 0.0009 Cracking and coking 0.0218 0.0098 Asphalt 0.0117 0.0053 Lube 0.0549 0.0248 Reforming and alkylation 0.0196 0.0088 English units (pounds per 1,000 bbl of feedstock) Phenolic compounds (4AAP): Crude 0.013 0.003 Cracking and coking 0.147 0.036 Asphalt 0.079 0.019 Lube 0.369 0.090 Reforming and alkylation 0.132 0.032 Total chromium: Crude 0.011 0.004 Cracking and coking 0.119 0.041 Asphalt 0.064 0.022 Lube 0.299 0.104 Reforming and alkylation 0.107 0.037 Hexavalent chromium: Crude 0.0007 0.0003 Cracking and coking 0.0076 0.0034 Asphalt 0.0041 0.0019 Lube 0.0192 0.0087 Reforming and alkylation 0.0069 0.0031 (2) See the comprehensive example in subpart D, § 419.43(c)(2). (d) The provisions of § 419.13(d) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (e) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (f) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BAT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.60 0.21 Hexavalent chromium 0.062 0.028 COD 1 360. 180. English units (pounds per 1,000 gallons of flow) Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0050 0.0018 Hexavalent chromium 0.00052 0.00023 COD 1 3.0 1.5 1 5 5 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.24 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). (a) Any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT): Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 (m 3 BOD 5 28.2 15.6 TSS 19.5 12.6 Oil and grease 8.4 4.5 pH ( 1 ( 1 English units (pounds per 1,000 bbl of feedstock) BOD 5 9.9 5.5 TSS 6.9 4.4 Oil and grease 3.0 1.6 pH ( 1 ( 1 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 0.91 25.0 to 49.9 0.95 50.0 to 74.9 1.04 75.0 to 99.9 1.13 100.0 to 124.9 1.23 125.0 to 149.9 1.35 150.0 or greater 1.41 (2) Process factor. Process configuration Process factor Less than 2.49 0.58 2.5 to 3.49 0.63 3.5 to 4.49 0.74 4.5 to 5.49 0.88 5.5 to 5.99 1.00 6.0 to 6.49 1.09 6.5 to 6.99 1.19 7.0 to 7.49 1.29 7.5 to 7.99 1.41 8.0 to 8.49 1.53 8.5 to 8.99 1.67 9.0 to 9.49 1.82 9.5 or greater 1.89 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The provisions of § 419.14(c) apply to discharge of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BCT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 48 26 TSS 33 21 Oil and grease 15 8 pH ( 1 ( 1 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 Oil and grease 0.13 0.067 pH ( 1 ( 1 1 [50 FR 28525, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.25 Pretreatment standards for existing sources (PSES). Except as provided in 40 CFR 403.7 and 403.13 any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for existing sources (PSES). The following standards apply to the total refinery flow contribution to the POTW: Pollutant or pollutant property Pretreatment standards for new sources—maximum for any 1 day Milligrams per liter (mg/l) Oil and grease 100 Ammonia 1 1 § 419.26 Standards of performance for new sources (NSPS). (a) Any new source subject to this subpart must achieve the following new source performance standards (NSPS): Pollutant or pollutant property NSPS effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 16.3 8.7 TSS 11.3 7.2 COD 1 118.0 61 oil and grease 4.8 2.6 Phenolic compounds 0.119 0.058 Ammonia (as N) 18.8 8.6 Sulfide 0.105 0.048 Total chromium 0.24 0.14 Hexavalent chromium 0.020 0.0088 pH ( 2 ( 2 English units (pounds per 1,000 bbl of feedstock) BOD 5 5.8 3.1 TSS 4.0 2.5 COD 1 41.5 21 Oil and grease 1.7 0.93 Phenolic compounds 0.042 0.020 Ammonia (as N) 6.6 3.0 Sulfide 0.037 0.017 Total chromium 0.084 0.049 Hexavalent chromium 0.0072 0.0032 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any 1 day and maximum average of daily values for 30 consecutive days. (1) Size Factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 0.91 25.0 to 49.9 0.95 50.0 to 74.9 1.04 75.0 to 99.9 1.13 100.0 to 124.9 1.23 125.0 to 149.9 1.35 150.0 or greater 1.41 (2) Process factor. Process configuration Process factor Less than 2.49 0.58 2.5 to 3.49 0.63 3.5 to 4.49 0.74 4.5 to 5.49 0.88 5.5 to 5.99 1.00 6.0 to 6.49 1.09 6.5 to 6.99 1.19 7.0 to 7.49 1.29 7.5 to 7.99 1.41 8.0 to 8.49 1.53 8.5 to 8.99 1.67 9.0 to 9.49 1.82 9.5 or greater 1.89 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The provisions of § 419.16(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (e) Effluent limitation for runoff. [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.27 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources (PSNS). (a) The following standards apply to the total refinery flow contribution to the POTW. Pollutant or pollutant property Pretreatment standards for new sources—maximum for any 1 day Milligrams per liter (mg/l) Oil and grease 100 Ammonia (as N) 1 1 (b) The following standard is applied to the cooling tower discharge part of the total refinery flow to the POTW by multiplying: (1) The standard; (2) by the total refinery flow to the POTW; and (3) by the ratio of the cooling tower discharge flow to the total refinery flow. Pollutant or pollutant property Pretreatment standards for new sources—maximum for any 1 day Milligrams per liter (mg/l) Total chromium 1 Subpart C—Petrochemical Subcategory § 419.30 Applicability; description of the petrochemical subcategory. The provisions of this subpart are applicable to all discharges from any facility that produces petroleum products by the use of topping, cracking, and petrochemical operations whether or not the facility includes any process in addition to topping, cracking, and petrochemical operations. The provisions of this subpart shall not be applicable, however, to facilities that include the processes specified in subpart D or E of this part. § 419.31 Specialized definitions. For the purpose of this subpart: (a) The general definitions, abbreviations, and methods of analysis set forth in part 401 of this chapter and the specialized definitions set forth in § 419.11 shall apply. (b) The term petrochemical operations i.e. i.e. § 419.32 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available. (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT): Pollutant or pollutant property BPT Effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 34.6 18.4 TSS 23.4 14.8 COD 1 210.0 109.0 Oil and grease 11.1 5.9 Phenolic compound 0.25 0.120 Ammonia as N 23.4 10.6 Sulfide 0.22 0.099 Total chromium 0.52 0.30 Hexavalent chromium 0.046 0.020 pH ( 2 ( 2 English units (pounds per 1,000 bbl of feedstock) BOD 5 12.1 6.5 TSS 8.3 5.25 COD 1 74.0 38.4 Oil and grease 3.9 2.1 Phenolic compounds 0.088 0.0425 Ammonia as N 8.25 3.8 Sufide 0.078 0.035 Total chromium 0.183 0.107 Hexavalent chromium 0.016 0.0072 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 barrels of feedstock per stream day Size factor Less than 24.9 0.73 25.0 to 49.9 0.76 50.0 to 74.9 0.83 75.0 to 99.9 0.91 100.0 to 124.9 0.99 125.0 to 149.9 1.08 150.0 or greater 1.13 (2) Process factor. Process configuration Process factor Less than 4.49 0.73 4.5 to 5.49 0.80 5.5 to 5.99 0.91 6.0 to 6.49 0.99 6.5 to 6.99 1.08 7.0 to 7.49 1.17 7.5 to 7.99 1.28 8.0 to 8.49 1.39 8.5 to 8.99 1.51 9.0 to 9.49 1.65 9.5 or greater 1.72 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The provisions of § 419.12(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease and 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease or 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BPT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 48. 26. TSS 33. 21. COD 1 360. 180. Oil and grease 15. 8. Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.73 0.43 Hexavalent chromium 0.062 0.028 pH ( 2 ( 2 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 COD 1 3.0 1.5 Oil and grease 0.13 0.067 Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0060 0.0035 Hexavalent chromium 0.00052 0.00023 pH ( 2 ( 2 1 5 5 2 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28522, 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.33 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available techology economically achievable (BAT): Pollutant or pollutant property BAT Effluent Limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 COD 1 210.0 109.0 Ammonia as N 23.4 10.6 Sulfide 0.22 0.099 English units (pounds per 1,000 bbl of feedstock) COD 1 74.0 38.4 Ammonia as N 8.25 3.8 Sulfide 0.078 0.035 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 0.73 25.0 to 49.9 0.76 50.0 to 74.9 0.83 75.0 to 99.9 0.91 100.0 to 124.9 0.99 125.0 to 149.9 1.08 150.0 or greater 1.13 (2) Process factor. Process configuration Process factor Less than 4.49 0.73 4.5 to 5.49 0.80 5.5 to 5.99 0.91 6.0 to 6.49 0.99 6.5 to 6.99 1.08 7.0 to 7.49 1.17 7.5 to 7.99 1.28 8.0 to 8.49 1.39 8.5 to 8.99 1.51 9.0 to 9.49 1.65 9.5 or greater 1.72 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c)(1) In addition to the provisions contained above pertaining to COD, ammonia and sulfide, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT): (i) For each of the regulated pollutant parameters listed below, the effluent limitation for a given refinery is the sum of the products of each effluent limitation factor times the applicable process feedstock rate, calculated as provided in 40 CFR 122.45(b). Applicable production processes are presented in appendix A, by process type. The process identification numbers presented in this appendix A are for the convenience of the reader. They can be cross-referenced in the Development Document for Effluent Limitations Guidelines, New Source Performance Standards, and Pretreatment Standards for the Petroleum Refining Point Source Category Pollutant or pollutant property and process type BAT effluent limitation factor Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 cubic meters of feedstock) Phenolic compounds (4AAP): Crude 0.037 0.009 Cracking and coking 0.419 0.102 Asphalt 0.226 0.055 Lube 1.055 0.257 Reforming and alkylation 0.377 0.092 Total chromium: Crude 0.030 0.011 Cracking and coking 0.340 0.118 Asphalt 0.183 0.064 Lube 0.855 0.297 Reforming and alkylation 0.305 0.106 Hexavalent chromium: Crude 0.0019 0.0009 Cracking and coking 0.0218 0.0098 Asphalt 0.0117 0.0053 Lube 0.0549 0.0248 Reforming and alkylation 0.0196 0.0088 English units (pounds per 1,000 bbl of feedstock) Phenolic compounds (4AAP): Crude 0.013 0.003 Cracking and coking 0.147 0.036 Asphalt 0.079 0.019 Lube 0.369 0.090 Reforming and alkylation 0.132 0.032 Total chromium: Crude 0.011 0.004 Cracking and coking 0.119 0.041 Asphalt 0.064 0.022 Lube 0.299 0.104 Reforming and alkylation 0.107 0.037 Hexavalent chromium: Crude 0.0007 0.0003 Cracking and coking 0.0076 0.0034 Asphalt 0.0041 0.0019 Lube 0.0192 0.0087 Reforming and alkylation 0.0069 0.0031 (2) See the comprehensive example in subpart D, § 419.43(c)(2). (d) The provisions of § 419.13(d) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (e) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (f) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BAT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.60 0.21 Hexavalent chromium 0.062 0.028 COD 1 360. 180. English units (pounds per 1,000 gallons of flow) Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0050 0.0018 Hexavalent chromium 0.00052 0.00023 COD 1 3.0 1.5 1 5 5 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.34 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). (a) Any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT): Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 34.6 18.4 TSS 23.4 14.8 Oil and grease 11.1 5.9 pH ( 1 ( 1 English units (pounds per 1,000 bbl of feedstock) BOD 5 12.1 6.5 TSS 8.3 5.25 Oil and grease 3.9 2.1 pH ( 1 ( 1 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 0.73 25.0 to 49.9 0.76 50.0 to 74.9 0.83 75.0 to 99.9 0.91 100.0 to 124.9 0.99 125.0 to 149.9 1.08 150.0 or greater 1.13 (2) Process factor. Process configuration Process factor Less than 4.49 0.73 4.5 to 5.49 0.80 5.5 to 5.99 0.91 6.0 to 6.49 0.99 6.5 to 6.99 1.08 7.0 to 7.49 1.17 7.5 to 7.99 1.28 8.0 to 8.49 1.39 8.5 to 8.99 1.51 9.0 to 9.49 1.65 9.5 or greater 1.72 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The provisions of § 419.14(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BCT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 48. 26. TSS 33. 21. Oil and grease 15. 8. pH ( 1 ( 1 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 Oil and grease 0.13 0.067 pH ( 1 ( 1 1 [50 FR 28526, July 12, 1985] § 419.35 Pretreatment standards for existing sources (PSES). Except as provided in 40 CFR 403.7 and 403.13 any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for existing sources (PSES). The following standards apply to the total refinery flow contribution to the POTW: Pollutant or pollutant property Pretreatment standards maximum for any 1 day (Milligrams per liter (mg/l)) Oil and grease 100 Ammonia (as N) 1 1 § 419.36 Standards of performance for new sources (NSPS). (a) Any new source subject to this subpart must achieve the following new source performance standards (NSPS): Pollutant or pollutant property NSPS Effluent Limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 21.8 11.6 TSS 14.9 9.5 COD 1 133.0 69.0 Oil and grease 6.6 3.5 Phenolic compounds 0.158 .077 Ammonia as N 23.4 10.7 Sulfide 0.140 0.063 Total chromium 0.32 0.19 Hexavalent chromium 0.025 0.012 pH ( 2 ( 2 English units (pounds per 1,000 bbl of feedstock) BOD 5 7.7 4.1 TSS 5.2 3.3 COD 1 47.0 24.0 Oil and grease 2.4 1.3 Phenolic compounds 0.056 0.027 Ammonia as N 8.3 3.8 Sulfide 0.050 0.022 Total chromium 0.116 0.068 Hexavalent chromium 0.0096 0.0044 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 24.9 0.73 25.0 to 49.9 0.76 50.0 to 74.9 0.83 75.0 to 99.9 0.91 100.0 to 124.9 0.99 125.0 to 149.9 1.08 150.0 or greater 1.13 (2) Process factor. Process configuration Process factor Less than 4.49 0.73 4.5 to 5.49 0.80 5.5 to 5.99 0.91 6.0 to 6.49 0.99 6.5 to 6.99 1.08 7.0 to 7.49 1.17 7.5 to 7.99 1.28 8.0 to 8.49 1.39 8.5 to 8.99 1.51 9.0 to 9.49 1.65 9.5 or greater 1.72 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The provisions of § 419.16(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (e) Effluent limitations for runoff. [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.37 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources (PSNS). (a) The following standards apply to the total refinery flow contribution to the POTW: Pollutant or pollutant property Pretreatment standards for new sources maximum for any 1 day Milligrams per liter (mg/l) Oil and grease 100 Ammonia (as N) 1 1 (b) The following standard is applied to the cooling tower discharge part of the total refinery flow to the POTW by multiplying: (1) The standard; (2) by the total refinery flow to the POTW; and (3) by the ratio of the cooling tower discharge flow to the total refinery flow. Pollutant or pollutant property Pretreatment standards for new sources maximum for any 1 day Miligrams per liter (mg/l) Total chromium 1 Subpart D—Lube Subcategory § 419.40 Applicability; description of the lube subcategory. The provisions of this subpart are applicable to all discharges from any facility that produces petroleum products by the use of topping, cracking, and lube oil manufacturing processes, whether or not the facility includes any process in addition to topping, cracking, and lube oil manufacturing processes. The provisions of this subpart are not applicable, however, to facilities that include the processes specified in subparts C and E of this part. § 419.41 Specialized definitions. The general definitions, abbreviations and methods of analysis set forth in part 401 of this chapter and the specialized definitions set forth in § 419.11 shall apply to this subpart. § 419.42 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT): Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 50.6 25.8 TSS 35.6 22.7 COD 1 360.0 187.0 Oil and grease 16.2 8.5 Phenolic compounds 0.38 0.184 Ammonia as N 23.4 10.6 Sulfide 0.33 0.150 Total chromium 0.77 0.45 Hexavalent chromium 0.068 0.030 pH ( 2 ( 2 English units (pounds per 1,000 bbl of feedstock) BOD 5 17.9 9.1 TSS 12.5 8.0 COD 1 127.0 66.0 Oil and grease 5.7 3.0 Phenolic compounds 0.133 0.065 Ammonia as N 8.3 3.8 Sulfide 0.118 0.053 Total chromium 0.273 0.160 Hexavalent chromium 0.024 0.011 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 49.9 0.71 50.0 to 74.9 0.74 75.0 to 99.9 0.81 100.0 to 124.9 0.88 125.0 to 149.9 0.97 150.0 to 174.9 1.05 175.0 to 199.9 1.14 200.0 or greater 1.19 (2) Process factor. Process configuration Process factor Less than 6.49 0.81 6.5 to 7.49 0.88 7.5 to 7.99 1.00 8.0 to 8.49 1.09 8.5 to 8.99 1.19 9.0 to 9.49 1.29 9.5 to 9.99 1.41 10.0 to 10.49 1.53 10.5 to 10.99 1.67 11.0 to 11.49 1.82 11.5 to 11.99 1.98 12.0 to 12.49 2.15 12.5 to 12.99 2.34 13.0 or greater 2.44 (3) Example of the application of the above factors. Example—Lube refinery 125, 000 bbl per stream day throughput. Calculation of the Process Configuration Process category Process included Weighting factor Crude Atm crude distillation 1 Cracking and coking Fluid cat. cracking 6 Lube Further defined in the development document 13 Asphalt Asphalt production 12 Process Capacity (1,000 bbl per stream day) Capacity relative to throughput Weighting Factor Processing configuration Crude: Atm 125.0 1.0 Vacuum 60.0 0.48 Desalting 125.0 1.0 Total 2.48 × 1 = 2.48 Cracking-FCC 41.0 0.328 Hydrocracking 20.0 0.160 Total 0.488 × 6 = 2.93 Lubes 5.3 0.042 4.0 0.032 4.9 0.039 Total 0.113 × 13 = 1.47 Asphalt 4.0 0.032 × 12 = .38 Refinery process configuration = 7.26 Notes: See table § 419.42(b)(2) for process factor. Process factor = 0.88. See table § 419.42(b)(1) for size factor for 125,000 bbl per stream day lube refinery. Size factor = 0.97. To calculate the limits for each parameter, multiply the limit § 419.42(a) by both the process factor and size factor. BOD5 limit (maximum for any 1 day) = 17.9 × 0.88 × 0.97 = 15.3 lb. per 1,000 bbl of feedstock. (c) The provisions of § 419.12(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease and 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease or 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BPT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 48. 26. TSS 33. 21. COD 1 360. 180. Oil and grease 15. 8. Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.73 0.43 Hexavalent chromium 0.062 0.028 pH ( 2 ( 2 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 COD 1 3.0 1.5 Oil and grease 0.13 0.067 Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0060 0.0035 Hexavalent chromium 0.00052 0.00023 pH ( 2 ( 2 1 5 5 2 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28522, 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.43 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT): Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per COD 1 360.0 187.0 Ammonia as N 23.4 10.6 Sulfide 0.33 0.150 English units (pounds per 1,000 bbl of feedstock) COD 1 127.0 66.0 Ammonia as N 8.3 3.8 Sulfide 0.118 0.053 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 49.9 0.71 50.0 to 74.9 0.74 75.0 to 99.9 0.81 100.0 to 124.9 0.88 125.0 to 149.9 0.97 150.0 to 174.9 1.05 175.0 to 199.9 1.14 200.0 or greater 1.19 (2) Process factor. Process configuration Process factor Less than 6.49 0.81 6.5 to 7.49 0.88 7.5 to 7.99 1.00 8.0 to 8.49 1.09 8.5 to 8.99 1.19 9.0 to 9.49 1.29 9.5 to 9.99 1.41 10.0 to 10.49 1.53 10.5 to 10.99 1.67 11.0 to 11.49 1.82 11.5 to 11.99 1.98 12.0 to 12.49 2.15 12.5 to 12.99 2.34 13.0 or greater 2.44 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c)(1) In addition to the provisions contained above pertaining to COD, ammonia and sulfide, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT): (i) For each of the regulated pollutant parameters listed below, the effluent limitation for a given refinery is the sum of the products of each effluent limitation factor times the applicable process feedstock rate, calculated as provided in 40 CFR 122.45(b). Applicable production processes are presented in appendix A, by process type. The process identification numbers presented in this appendix A are for the convenience of the reader. They can be cross-referenced in the Development Document for Effluent Limitations Guidelines, New Source Performance Standards, and Pretreatment Standards for the Petroleum Refining Point Source Category Pollutant or pollutant property and process type BAT effluent limitation factor Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 Phenolic compounds (4AAP): Crude 0.037 0.009 Cracking and coking 0.419 0.102 Asphalt 0.226 0.055 Lube 1.055 0.257 Reforming and alkylation 0.377 0.092 Total chromium: Crude 0.030 0.011 Cracking and coking 0.340 0.118 Asphalt 0.183 0.064 Lube 0.855 0.297 Reforming and alkylation 0.305 0.106 Hexavalent chromium: Crude 0.0019 0.0009 Cracking and coking 0.0218 0.0098 Asphalt 0.0117 0.0053 Lube 0.0549 0.0248 Reforming and alkylation 0.0196 0.0088 English units (pounds per 1,000 bbl of feedstock) Phenolic compounds (4AAP): Crude 0.013 0.003 Cracking and coking 0.147 0.036 Asphalt 0.079 0.019 Lube 0.369 0.090 Reforming and alkylation 0.132 0.032 Total chromium: Crude 0.011 0.004 Cracking and coking 0.119 0.041 Asphalt 0.064 0.022 Lube 0.299 0.104 Reforming and alkylation 0.107 0.037 Hexavalent chromium: Crude 0.0007 0.0003 Cracking and coking 0.0076 0.0034 Asphalt 0.0041 0.0019 Lube 0.0192 0.0087 Reforming and alkylation 0.0069 0.0031 (2) Example Application of Effluent Limitations Guidelines as Applicable to Phenolic Compounds, Hexavalent Chromium, and Total Chromium. The following example presents the derivation of a BAT phenolic compound (4AAP) effluent limitation (30-day average) for a petroleum refinery permit. The methodology is also applicable to hexavalent chromium and total chromium. Refinery process Process feedstock rate 1,000 bbl/day 1. Atmospheric crude distillation 100 2. Crude desalting 50 3. Vacuum crude distillation 75 Total crude processes (C) 225 6. Fluid catalytic cracking 25 10. Hydrocracking 20 Total cracking and coking processes (K) 45 18. Asphalt production 5 Total asphalt processes (A) 5 21. Hydrofining 3 Total lube processes (L) 3 8. Catalytic reforming 10 Total reforming and alkylation processes (R) 10 Note: 30 day average effluent limitation for phenolic compounds (4AAP), lb/day = (0.003) (225) + (0.036) (45) + (0.019) (5) + (0.090) (3) + (0.032) (10) = 2.98 lb/day. (d) The provisions of § 419.13(d) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (e) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (f) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BAT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.60 0.21 Hexavalent chromium 0.062 0.028 COD 1 360. 180. English units (pounds per 1,000 gallons of flow) Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0050 0.0018 Hexavalent chromium 0.00052 0.00023 COD 1 3.0 1.5 1 5 5 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, 28524, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.44 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). (a) Any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT): Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 50.6 25.8 TSS 35.6 22.7 Oil and Grease 16.2 8.5 pH ( 1 ( 1 English units (pounds per 1,000 bbl of feedstock) BOD 5 17.9 9.1 TSS 12.5 8.0 Oil and Grease 5.7 3.0 pH ( 1 ( 1 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 49.9 0.71 50.0 to 74.9 0.74 75.0 to 99.9 0.81 100.0 to 124.9 0.88 125.0 to 149.9 0.97 150.0 to 174.9 1.05 175.0 to 199.9 1.14 200.0 or greater 1.19 (2) Process factor. Process configuration Process factor Less than 6.49 0.81 6.5 to 7.49 0.88 7.5 to 7.99 1.00 8.0 to 8.49 1.09 8.5 to 8.99 1.19 9.0 to 9.49 1.29 9.5 to 9.99 1.41 10.0 to 10.49 1.53 10.5 to 10.99 1.67 11.0 to 11.49 1.82 11.5 to 11.99 1.98 12.0 to 12.49 2.15 12.5 to 12.99 2.34 13.0 or greater 2.44 (c) The provisions of § 419.14(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BCT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric unit (kilograms per 1,000 m 3 BOD 5 48. 26. TSS 33. 21. Oil and grease 15. 8. pH ( 1 ( 1 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 Oil and grease 0.13 0.067 pH ( 1 ( 1 1 [50 FR 28526, July 12, 1985] § 419.45 Pretreatment standards for existing sources (PSES). Except as provided in 40 CFR 403.7 and 403.13 any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for existing sources (PSES). The following standards apply to the total refinery flow contribution to the POTW: Pollutant or pollutant property Pretreatment standards for existing sources—maximum for any 1 day Milligrams per liter (mg/l) Oil and grease 100 Ammonia (as N) 1 1 § 419.46 Standards of performance for new sources (NSPS). (a) Any new source subject to this subpart must achieve the following new source performance standards (NSPS): Pollutant or pollutant property NSPS effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 34.6 18.4 TSS 23.4 14.9 COD 1 245.0 126.0 Oil and grease 10.5 5.6 Phenolic compounds 0.25 0.12 Ammonia as N 23.4 10.7 Sulfide 0.220 0.10 Total chromium 0.52 0.31 Hexavalent chromium 0.046 0.021 pH ( 2 ( 2 English units (pounds per 1,000 bbl of feedstock) BOD 1 12.2 6.5 TSS 8.3 5.3 COD 1 87.0 45.0 Oil and grease 3.8 2.0 Phenolic compounds 0.088 0.043 Ammonia as N 8.3 3.8 Sulfide 0.078 0.035 Total chromium 0.180 0.105 Hexavalent chromium 0.022 0.0072 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 49.9 0.71 50.0 to 74.9 0.74 75.0 to 99.9 0.81 100.0 to 124.9 0.88 125.0 to 149.9 0.97 150.0 to 174.9 1.05 175.0 to 199.9 1.14 200.0 or greater 1.19 (2) Process factor. Process configuration Process factor Less than 6.49 0.81 6.5 to 7.49 0.88 7.5 to 7.99 1.00 8.0 to 8.49 1.09 8.5 to 8.99 1.19 9.0 to 9.49 1.29 9.5 to 9.99 1.41 10.0 to 10.49 1.53 10.5 to 10.99 1.67 11.0 to 11.49 1.82 11.5 to 11.99 1.98 12.0 to 12.49 2.15 12.5 to 12.99 2.34 13.0 or greater 2.44 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The provisions of § 419.16(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provision of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/1. (e) Effluent Limitations for Runoff. [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, 28528, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.47 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources (PSNS). (a) The following standards apply to the total refinery flow contribution to the POTW: Pollutant or pollutant property Pretreatment standards for new sources, maximum for any 1 day Milligrams per liter (mg/l) Oil and grease 100 Ammonia (as N) 1 1 (b) The following standard is applied to the cooling tower discharge part of the total refinery flow to the POTW by multiplying: (1) The standard; (2) by the total refinery flow to the POTW; and (3) by the ratio of the cooling tower discharge flow to the total refinery flow. Pollutant or pollutant property Pretreatment standards for new sources, maximum for any 1 day Milligrams per liter (mg/l) Total chromium 1 Subpart E—Integrated Subcategory § 419.50 Applicability; description of the integrated subcategory. The provisions of this subpart are applicable to all discharges resulting from any facility that produces petroleum products by the use of topping, cracking, lube oil manufacturing processes, and petrochemical operations, whether or not the facility includes any process in addition to topping, cracking, lube oil manufacturing processes, and petrochemical operations. § 419.51 Specialized definitions. The general definitions, abbreviations, and methods of analysis set forth in part 401 of this chapter and the specialized definitions set forth in § 419.31 shall apply to this subpart. § 419.52 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT). (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT): Pollutant or pollutant property BPT Effluent Limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 54.4 28.9 TSS 37.3 23.7 COD 1 388.0 198.0 Oil and grease 17.1 9.1 Phenolic compounds 0.40 0.192 Ammonia as N 23.4 10.6 Sulfide 0.35 0.158 Total Chromium 0.82 0.48 Hexavalent chromium 0.068 0.032 pH ( 2 ( 2 English units (pounds per 1,000 bbl of feedstock) BOD 1 19.2 10.2 TSS 13.2 8.4 COD 1 136.0 70.0 Oil and grease 6.0 3.2 Phenolic compounds 0.14 0.068 Ammonia as N 8.3 3.8 Sulfide 0.124 0.056 Total chromium 0.29 0.17 Hexavalent chromium 0.025 0.011 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 124.9 0.73 125.0 to 149.9 0.76 150.0 to 174.9 0.83 175.0 to 199.9 0.91 200.0 to 224.9 0.99 225 or greater 1.04 (2) Process factor. Process configuration Process factor Less than 6.49 0.75 6.5 to 7.49 0.82 7.5 to 7.99 0.92 8.0 to 8.49 1.00 8.5 to 8.99 1.10 9.0 to 9.49 1.20 9.5 to 9.99 1.30 10.0 to 10.49 1.42 10.5 to 10.99 1.54 11.0 to 11.49 1.68 11.5 to 11.99 1.83 12.0 to 12.49 1.99 12.5 to 12.99 2.17 13.0 or greater 2.26 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The provisions of § 419.12(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provision of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease and 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease or 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BPT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 48. 26. TSS 33. 21. COD 1 360. 180. Oil and grease 15. 8. Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.73 0.43 Hexavalent chromium 0.062 0.028 pH ( 2 ( 2 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 COD 1 3.0 1.5 Oil and grease 0.13 0.067 Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0060 0.0035 Hexavalent chromium 0.00052 0.00023 pH ( 2 ( 2 1 5 5 2 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28522, 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.53 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT). (a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT): Pollutant or pollutant property BAT Effluent Limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 COD 1 388.0 198.0 Ammonia as N 23.4 10.6 Sulfide 0.35 0.158 English units (pounds per 1,000 bbl of feedstock) COD 1 136.0 70.0 Ammonia as N 8.3 3.8 Sulfide 0.124 0.056 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 124.9 0.73 125.0 to 149.9 0.76 150.0 to 174.9 0.83 175.0 to 199.9 0.91 200 to 224.9 0.99 225 or greater 1.04 (2) Process factor. Process configuration Process factor Less than 6.49 0.75 6.5 to 7.49 0.82 7.5 to 7.99 0.92 8.0 to 8.49 1.00 8.5 to 8.99 1.10 9.0 to 9.49 1.20 9.5 to 9.99 1.30 10.0 to 10.49 1.42 10.5 to 10.99 1.54 11.0 to 11.49 1.68 11.5 to 11.99 1.83 12.0 to 12.49 1.99 12.5 to 12.99 2.17 13.0 or greater 2.26 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c)(1) In addition to the provisions contained above pertaining to COD, ammonia and sulfide, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT): (i) For each of the regulated pollutant parameters listed below, the effluent limitation for a given refinery is the sum of the products of each effluent limitation factor times the applicable process feedstock rate, calculated as provided in 40 CFR 122.45(b). Applicable production processes are presented in appendix A, by process type. The process identification numbers presented in this appendix A are for the convenience of the reader. They can be cross-referenced in the Development Document for Effluent Limitations Guidelines, New Source Performance Standards, and Pretreatment Standards for the Petroleum Refining Point Source Category Pollutant or pollutant property and process type BAT effluent limitation factor Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 cubic meters of feedstock) Phenolic compounds (4AAP): Crude 0.037 0.009 Cracking and coking 0.419 0.102 Asphalt 0.226 0.055 Lube 1.055 0.257 Reforming and alkylation 0.377 0.092 Total chromium: Crude 0.030 0.011 Cracking and coking 0.340 0.118 Asphalt 0.183 0.064 Lube 0.855 0.297 Reforming and alkylation 0.305 0.106 Hexavalent chromium: Crude 0.0019 0.0009 Cracking and coking 0.0218 0.0098 Asphalt 0.0117 0.0053 Lube 0.0549 0.0248 Reforming and alkylation 0.0196 0.0088 English units (pounds per 1,000 bbl of feedstock) Phenolic compounds (4AAP): Crude 0.013 0.003 Cracking and coking 0.147 0.036 Asphalt 0.079 0.019 Lube 0.369 0.090 Reforming and alkylation 0.132 0.032 Total chromium: Crude 0.011 0.004 Cracking and coking 0.119 0.041 Asphalt 0.064 0.022 Lube 0.299 0.104 Reforming and alkylation 0.107 0.037 Hexavalent chromium: Crude 0.0007 0.0003 Cracking and coking 0.0076 0.0034 Asphalt 0.0041 0.0019 Lube 0.0192 0.0087 Reforming and alkylation 0.0069 0.0031 (2) See the comprehensive example in subpart D, § 419.43(c)(2). (d) The provisions of § 419.13(d) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (e) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (f) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BAT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 Phenolic compounds (4AAP) 0.35 0.17 Total chromium 0.60 0.21 Hexavalent chromium 0.062 0.028 COD 1 360. 180. English units (pounds per 1,000 gallons of flow) Phenolic compounds (4AAP) 0.0029 0.0014 Total chromium 0.0050 0.0018 Hexavalent chromium 0.00052 0.00023 COD 1 3.0 1.5 1 5 5 [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.54 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). (a) Any existing point subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT): Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 54.4 28.9 TSS 37.3 23.7 Oil and grease 17.1 9.1 pH ( 1 ( 1 English units (pounds per 1,000 bbl of feedstock) BOD 5 19.2 10.2 TSS 13.2 8.4 Oil and grease 6.0 3.2 ph ( 1 ( 1 1 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 124.9 0.73 125.0 to 149.9 0.76 150.0 to 174.9 0.83 175. to 199.9 0.91 200.0 to 224.9 0.99 225.0 or greater 1.04 (2) Process factor. Process configuration Process factor Less than 6.49 0.75 6.5 to 7.49 0.82 7.5 to 7.99 0.92 8.0 to 8.49 1.00 8.5 to 8.99 1.10 9.0 to 9.49 1.20 9.5 to 9.99 1.30 10.0 to 10.49 1.42 10.5 to 10.99 1.54 11.0 to 11.49 1.68 11.5 to 11.99 1.83 12.0 to 12.49 1.99 12.5 to 12.99 2.17 13.0 or greater 2.26 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The provisions of § 419.14(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. (e) Effluent limitations for contaminated runoff. (1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease based upon an analysis of any single grab or composite sample. (2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: Pollutant or pollutant property BCT effluent limitations for contaminated runoff Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 48. 26. TSS 33. 21. Oil and grease 15. 8. pH ( 1 ( 1 English units (pounds per 1,000 gallons of flow) BOD 5 0.40 0.22 TSS 0.28 0.18 Oil and grease 0.13 0.067 pH ( 1 ( 1 1 [50 FR 28527, July 12, 1985] § 419.55 Pretreatment standards for existing sources (PSES). Except as provided in 40 CFR 403.7 and 403.13 any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR 403 and achieve the following pretreatment standards for existing sources (PSES). The following standards apply to the total refinery flow contribution to the POTW: Pollutant or pollutant property Pretreatment standards for existing sources—maximum for any 1 day Milligrams per liter (mg/l) Oil and grease 100 Ammonia (as N) 1 1 § 419.56 Standards of performance for new sources (NSPS). (a) Any new source subject to this subpart must achieve the following new source performance standards (NSPS): Pollutant or pollutant property NSPS effluent limitation Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed Metric units (kilograms per 1,000 m 3 BOD 5 41.6 22.1 TSS 28.1 17.9 COD 1 295.0 152.0 Oil and grease 12.6 6.7 Phenolic compounds 0.30 0.14 Ammonia as N 23.4 10.7 Sulfide 0.26 0.12 Total chromium 0.64 0.37 Hexavalent chromium 0.052 0.024 pH ( 2 ( 2 English units (pounds per 1,000 bbl of feedstock) BOD 5 14.7 7.8 TSS 9.9 6.3 COD 1 104.0 54.0 Oil and grease 4.5 2.4 Phenolic compounds 0.105 0.051 Ammonia as N 8.3 3.8 Sulfide 0.093 0.042 Total chromium 0.220 0.13 Hexavalent chromium 0.019 0.0084 pH ( 2 ( 2 1 2 (b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days. (1) Size factor. 1,000 bbl of feedstock per stream day Size factor Less than 124.9 0.73 125.0 to 149.9 0.76 150.0 to 174.9 0.83 175.0 to 199.9 0.91 200 to 224.9 0.99 225 or greater 1.04 (2) Process factor. Process configuration Process factor Less than 6.49 0.75 6.5 to 7.49 0.82 7.5 to 7.99 0.92 8.0 to 8.49 1.00 8.5 to 8.99 1.10 9.0 to 9.49 1.20 9.5 to 9.99 1.30 10.0 to 10.49 1.42 10.5 to 10.99 1.54 11.0 to 11.49 1.68 11.5 to 11.99 1.83 12.0 to 12.49 1.99 12.5 to 12.99 2.17 13.0 or greater 2.26 (3) See the comprehensive example in subpart D, § 419.42(b)(3). (c) The provisions of § 419.16(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provision of this subpart. (d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l. (e) Effluent limitations for runoff. [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28523, 28528, July 12, 1985; 50 FR 32414, Aug. 12, 1985] § 419.57 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources (PSNS). (a) The following standards apply to the total refinery flow contribution to the POTW: Pollutant or pollutant property Pretreatment standards for new sources—maximum for any 1 day Milligrams per liter (mg/l) Oil and grease 100 Ammonia (as N) 1 1 (b) The following standard is applied to the cooling tower discharge part of the total refinery flow to the POTW by multiplying: (1) The standards; (2) by the total refinery flow to the POTW; and (3) by the ratio of the cooling tower discharge flow to the total refinery flow. Pollutant or pollutant property Pretreatment standards for new sources—maximum for any 1 day Milligrams per liter (mg/1) Total chromium 1 Appendix A to Part 419—Processes Included in the Determination of BAT Effluent Limitations for Total Chromium, Hexavalent Chromium, and Phenolic Compounds (4AAP) Crude Processes 1. Atmospheric Crude Distillation 2. Crude Desalting 3. Vacuum Crude Distillation Cracking and Coking Processes 4. Visbreaking 5. Thermal Cracking 6. Fluid Catalytic Cracking 7. Moving Bed Catalytic Cracking 10. Hydrocracking 15. Delayed Coking 16. Fluid Coking 54. Hydrotreating Asphalt Processes 18. Asphalt Production 32. 200 °F Softening Point Unfluxed Asphalt 43. Asphalt Oxidizing 89. Asphalt Emulsifying Lube Processes 21. Hydrofining, Hydrofinishing, Lube Hydrofining 22. White Oil Manufacture 23. Propane Dewaxing, Propane Deasphalting, Propane Fractioning, Propane Deresining 24. Duo Sol, Solvent Treating, Solvent Extraction, Duotreating, Solvent Dewaxing, Solvent Deasphalting 25. Lube Vac Twr, Oil Fractionation, Batch Still (Naphtha Strip), Bright Stock Treating 26. Centrifuge and Chilling 27. MEK Dewaxing, Ketone Dewaxing, MEK-Toluene Dewaxing 28. Deoiling (wax) 29. Naphthenic Lubes Production 30. SO 2 34. Wax Pressing 35. Wax Plant (with Neutral Separation) 36. Furfural Extraction 37. Clay Contacting—Percolation 38. Wax Sweating 39. Acid Treating 40. Phenol Extraction Reforming and Alkylation Processes 8. H 2 4 12. Catalytic Reforming [50 FR 28528, July 12, 1985; 50 FR 32414, Aug. 12, 1985]

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